In story mode, there are certain characters you can control that are noticeable unavailable in versus mode. To unlock these characters, you must finish their three required levels, the last one being a boss fight. Some of these fights unlock two characters at once.
Defeat Altered Thing in Human Torch's third mission ("Old Friends")
Iron Man
Defeat Brigade in Iron Man's third mission
Brigade
Defeat Brigade in Iron Man's third mission
Fault Zone
Defeat Fault Zone in Storm's third mission ("Earthquake!")
Storm
Defeat Fault Zone in Storm's third mission ("Earthquake!")
Hazmat
Defeat Hazmat in Magneto's third mission
Magneto
Defeat Hazmat in Magneto's third mission
Daredevil
Defeat Johnny Ohm in Daredevil's third mission ("The Electric Man")
Venom
Defeat Solara in Venom's third mission
Solara
Defeat Solara in Venom's third mission
Niles Van Roekel
Finish story mode
Paragon
Finish story mode
1/3/2006
Unlock Characters Without Story Battles
1. Go to versus 2. Life match, one life each. You can do 1 vs com or 1 vs 2 3. Choose Bridge stage 4. Repeatedly go to either side and jump off of the bridge, choose rematch 5. Every ten battles you earn a new Venue or Character
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